From News Desk
In a new study, MIT researchers have measured lithium intercalation rates in a variety of different battery materials and used that data to develop a new model of how the reaction is controlled. Their model suggests that lithium intercalation is governed by a process known as coupled ion-electron transfer, in which an electron is transferred to the electrode along with a lithium ion.
At the heart of all lithium-ion batteries is a simple reaction – Lithium ions dissolved in an electrolyte solution “intercalate” or insert themselves into a solid electrode during battery discharge. When they de-intercalate and return to the electrolyte, the battery charges.
This process happens thousands of times throughout the life of a battery. The amount of power that the battery can generate, and how quickly it can charge, depend on how fast this reaction happens. However, little is known about the exact mechanism of this reaction, or the factors that control its rate.
Insights gleaned from this model could guide the design of more powerful and faster charging lithium-ion batteries, the researchers say.
“What we hope is enabled by this work is to get the reactions to be faster and more controlled, which can speed up charging and discharging,” says Martin Bazant, the Chevron Professor of Chemical Engineering and a professor of mathematics at MIT.
The new model may also help scientists understand why tweaking electrodes and electrolytes in certain ways leads to increased energy, power, and battery life — a process that has mainly been done by trial and error.
“This is one of these papers where now we began to unify the observations of reaction rates that we see with different materials and interfaces, in one theory of coupled electron and ion transfer for intercalation, building up previous work on reaction rates,” says Yang Shao-Horn, the JR East Professor of Engineering at MIT and a professor of mechanical engineering, materials science and engineering; and chemistry.
Shao-Horn and Bazant are the senior authors of the paper. The paper’s lead authors are Yirui Zhang PhD ’22, who is now an assistant professor at Rice University; Dimitrios Fraggedakis PhD ’21, who is now an assistant professor at Princeton University; Tao Gao, a former MIT postdoc who is now an assistant professor at the University of Utah; and MIT graduate student Shakul Pathak.
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